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Donnish Journal of Pure and Applied Chemistry

April 2015 Vol. 1(1), pp. 001-007

Copyright 2015 Donnish Journals




Original Research Paper


Synthesis and Characterization of Cu+2, Ni+2 Heteronuclear Complexes with Macrocyclic (N2O2, N2S2) Type Ligands


1Ashour H. Dawood*, 2Hussain A. Mohammad and 2Tariq. H. Almgheer

1College of Pharmacy, Al Mustansiriya University, Baghdad, Iraq.
2College of Science, Babylon University, Iraq.

Corresponding Author E-mail: nurhalimshahib@yahoo.com

Accepted 16th March, 2015.



Abstract


The heteronuclear of divalent nickel and copper complexes were prepared through the template reaction with the prepared precursors, which were synthesised via the reaction of benzoyl acetone. With o-amino phenol and o-amino thiophenol respectively as Schiff base compounds, the prepared complexes and precursors were characterised by IR, UV, Mass and 1H NMR, 13C NMR spectroscopies, the elemental micro analysis C. H. N. S and Atomic absorption was carried out. The physical measurements were tailed m.p, solubility and magnetic susceptibility. The measurements show the suggested geometry of complexes is square planar (D4h) geometry around the metal ions.

Keywords: Heteronuclear, Macrocyclic compounds.

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Cite This Article:

Ashour H. Dawood, Hussain A. Mohammad and Tariq. H. Almgheer. Synthesis and Characterization of Cu+2, Ni+2 Heteronuclear Complexes with Macrocyclic (N2O2, N2S2) Type Ligands. Donnish Journal of Pure and Applied Chemistry 1(1) 2015 pp. 001-007.


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